Thursday, 10 November 2016

Stoichiometry



According to dictionary of chemistry "Stoichiometry" is the numerical relationship of elements and compounds as reactants and products in chemical reactions. So in this article, I would like to present the basic concept of Stoichiometry.

A. Relative atomic mass (Ar)

The relative mass of an atom based on a scale in which a specific carbon atom (carbon-12) is assigned a mass value of 12.

Example

A sample of gallium contains 60% of atoms of 69Ga and 40% of atoms of 71Ga. Calculate the relative atomic mass of this sample of gallium.


B. Relative formula mass (Mr)

Since atoms are so tiny, we use large groups of atoms (moles of atoms) to east our calculation. The formula for a compound contains much information of use to the chemist, including the number of atoms of each element in a formula unit of a compound.

In this article I will not use the term “Relative molecular mass”. The word molecule or the general term formula unit may applied to one unit of H2O. The word atom or the term formula unit may applied to one unit of uncombined Pt. However, there is no special name for one unit of NaCl. Formula unit  is the best designation. (Some texts refer to “molecule” of NaCl, and especially to “molecular mass” of NaCl, because the calculations done on formula units do not depend on the type of bonding involved. However, the terms molecule and molecular mass should be reserved for substances bonded into molecules).

The term “formula mass” is correctly used for either ionic or molecular substances. Relative formula mass of a compound is the sum of the atomic masses of all atoms in the formula.  

Example :
1. What is the formula mass of CaSO­4?

2. What is the formula mass of Mg(NO3)2

C. The mole
The amount of substance that contains the mass in grams numerically equal to its formula mass in amu (atomic mass unit) contains 6.022 × 1023 formula units, or one mole of the substance. This is sometimes called the molar mass of the substance. Molar mass is numerically equal to the formula mass of the substance (the atomic mass for atoms of elements) and has the units grams/mole.

1. How many moles of substance are there in 111 grams of F2?

2. Calculate the mass of 2.50 mol NaClO4.

2 comments:

  1. Finally! thank you so much this really helps. If you don't mind, would you post more about other different chemistry topics?

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    1. Thanks for commenting,, I'll try my best,, don't forget to share :),,

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